Gary Woodland gets his U.S. Open title defence under way at 13.05 on Thursday at Winged Foot Golf Club.
The American won his first Major at Pebble Beach last year and will be joined Open champion Shane Lowry and amateur Andy Ogletree for the first two rounds,
New Zealand's Ryan Fox is in the first group out at 06.50 along with Australia's Curtis Luck and American Brandon Wu.
In-form Dane Rasmus Højgaard makes his Major Championship debut at 07.01 in the company of Americans Joel Dahmen and J.T. Poston.
Martin Kaymer, who finished third and second on his last two European Tour outings, begins his quest for a third Major title at 07.23, with Jimmy Walker and John Augenstein alongside him.
England's Tyrrell Hatton is joined by Major winners Henrik Stenson and Danny Willett in the 07.45 grouping, with Jason Day, Sergio Garcia and Webb Simpson out 11 minutes later.
Collin Morikawa's bid to land back-to-back Majors starts at 08.07 in the company of Justin Thomas and Tiger Woods, with Rory McIlroy, Adam Scott and Justin Rose out at the same time from the tenth tee.
World Number Two Jon Rahm tees off alongside Paul Casey and Phil Mickelson at 13.27, while Spain's Adrian Otaegui is in the last group out at 14.11 with German Stephan Jaeger and American Lee Hodges.
