Defending championTyrrell Hattonwill reunite with actorJamie Dornanas he returns to St Andrews on Thursday.
The Englishman played alongside Northern Irishman Dornan on his way to a first European Tour title last year, with the duo starting on the Old Course at 11.12 on Thursday.
Rory McIlroywill play in the company of his father,Gerry, at 09.22 as the four-time Major Champion aims to better his three previous runner-up finishes in the event.
Former championLee Westwoodis set to tee it up with singerRonan Keatingat 11.23, 14 years on from his last victory here.
Westwood’s Ryder Cup teammateGraeme McDowellwill play with retired jockeyAP McCoy at 09.44, the duo now a regular pairing in the annual Pro-Am event.
Padraig HarringtonandJP McManuswill aim to win the team competition for a record third time and begin at 09.55.
Martin Kaymerwill continue his run of playing alongside family and is partnered by his brother,Philip, this year after playing with father, Horst, in 2016.
Sky Sports pundit and former Liverpool footballerJamie Redknappwill joinLuke Donald at 10.17.
Ricardo Gouveiawill tee it up alongside compatriotLuis Figoat 09.00 at Carnoustie’s Championship Course, with Callum Shinkwinand former England cricketerKevin Pietersenunder way on the same course at 09.33.
Click here for a full list of tee times.